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Salicylic Acid
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Salicylic acid is more acidic than o-methoxybenzoic acid though both have electron releasing groups i.e., -OH and -OCH3 . This is because (a) -OH is a stronger electron releasing group compared to -OCH3. (b) salicylate ion is stabilized by intramolecular hydrogen bonding. (c) salicylic acid has two replaceable hydrogen atoms. (d) -OCH3 has a stronger steric effect to prevent the stabilization of the carboxylate anion. | Numerade
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SOLVED: In your pharmaceutical formulation, benzoic acid is mixed with salicylic acid in a roughly 2:1 ratio. If you measured the melting point of this mixture, would the benzoic acid melt at a temperature that is the same as pure benzoic acid, or would it melt at a lower than that of pure benzoic acid or at a higher temperature than that of pure benzoic acid?
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