This is followed by an intramolecular proton transfer ... including groundbreaking concepts, mechanisms, methods, materials, reactions, and applications. All articles are diamond open access ...

This transformation relies on radical mechanisms based on hydrogen ... a radical cation that initiates the intramolecular C(sp3)–N bond forming reaction. “HFIP is a fascinating yet intriguing ...

Although vinyl cations have been studied for more than 50 years, until now their use as reagents was limited to intramolecular reactions and reactions with heteroatom solvents. Because they are so ...

Experimental evidence suggests that this reaction occurs at the gas-liquid interface of microdroplets, but its microscopic mechanism has not been elucidated ... followed by reduction by one electron, ...