This transformation relies on radical mechanisms based on hydrogen ... a radical cation that initiates the intramolecular C(sp3)–N bond forming reaction. “HFIP is a fascinating yet intriguing ...

To address the reaction mechanisms that could plausibly explain ... In short, the dehydrogenation of the β-ethyl groups followed by the intramolecular electrocyclization of the resulting ethenyl ...

This is followed by an intramolecular proton transfer ... including groundbreaking concepts, mechanisms, methods, materials, reactions, and applications. All articles are diamond open access ...