Contributed by Chi-Ming Che; received October 6, 2023; accepted April 27, 2024; reviewed by Harry B. Gray and Yi Lu ...

A new ‘super-shielded’ carbene is stable in liquid water solutions. The US team that made the carbene claims that it ‘unambiguously confirms’ that it is possible to generate carbenes in an aqueous ...

In soccer, the objective is simple: score more goals than your opponent over 90 minutes. Each team starts with 11 players, including defenders to block attacks, midfielders to create chances, and ...

Synthesis and determination of 7′.(A) Synthesis of carbenoid 6′ and carbene 7′.The reaction is clean and quantitative when LiHMDS is used as a base and pure THF as the solvent. (B) Three ...

Based on the comparisons, they found that plutonium’s bonding to the alkylidene and N-heterocyclic carbene ligands was more covalent than predicted, hinting that f-block elements’ behavior isn ...

This discount is shown at checkout, if applicable. The first example of a stable, doubly oxidized carbene has been made by chemists in pursuit of octet-rule-defying molecules. Most carbon atoms ...

Carbene-transfer reactions involve a precursor ... pathways for the production of diazo-containing metabolites in engineered microbial strains is an exciting advance,’ he says. ‘As new examples of ...

Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, 30 South Puzhu Road, Nanjing ...

The scope of laboratory-evolved biocatalytic carbene transfer reactions. Engineered heme proteins catalyze a broad range of abiological reactions with diazo reagents. These reactions are assumed to ...

Figure 3: Carbene footprinting of USP5 reveals di-ubiquitin ... The importance of W62, for example, in making van der Waals contacts with a sugar ring in the oligomeric substrate has been ...