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This process requires a catalyst that preferentially binds and hydrogenates alkynes but shuns alkenes, sparing double-bonded carbons from further hydrogenation into unwanted alkanes. One option is ...
The 1-dodecene intermediate showed limited isomerization. Remarkably, the hydrogenation of the alkene intermediate could lead to the formation of 1-dodecane. However, only after 240 minutes of ...
The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.organomet.1c00053. Smart citations by scite.ai include citation ...
The team’s alkene hydrogenation reaction runs differently depending on whether they activate the catalyst with heat or light (ACS Catal 2020, DOI: 10.1021/acscatal.0c05136).
Radical hydrogenation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane isomers. Current single-catalyst methods require ...
KEYWORDS: Alkene Hydrogenation, Benzyl Ether, Benzyl Ester, N-Benzyl Group. JOURNAL NAME: International Journal of Organic Chemistry, Vol.6 No.1, March 4, 2016 ABSTRACT: NaBH4, CH3CO2H, Pd/C has been ...
Here we report that graphene (a single layer of one-atom-thick carbon atoms) can replace metals for hydrogenation of carbon–carbon multiple bonds. Besides alkene hydrogenation, we have shown ...
Shielding Pt/γ-Mo 2 N by inert nano-overlays enables stable H 2 production The strong ligand effects exerted by the supports distinguish supported metal clusters from extended metal surfaces ...
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