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3 年
常用手性膦配体----JosiPhos
这一发现让Togni和Spindler共同产生了利用仲膦(e.g., HPCy2)合成含有不同PR2基团的新的 螯合配体的想法。第一个JosiPhos(X = H)以第一个合成他的技术员Josi Puleo的名字命名,此后发展出的一大类类似结构的配体也称为JosiPhos【 Topics in Catalysis , 2002, 19, 3-16】。 JosiPhos类 ...
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