The first catalytic enantioselective Roskamp reaction of α-alkyl-α-diazoesters with aromatic aldehydes was realized using a simple chiral N,N′-dioxide−scandium(III) complex. Remarkably, with 0.05 mol ...

Density functional theory (DFT) calculations at the B3LYP/6-31G(d,p) (LANL2DZ for Zr) level of theory were performed to elucidate the reaction mechanism for the reduction of amides to aldehydes using ...

A mild and efficient method for the chemoselective synthesis of acylals from aromatic aldehydes and their deprotections catalyzed by sulfated zirconia. Authorship SCIMAGO INSTITUTIONS RANKINGS.