This transformation relies on radical mechanisms based on hydrogen ... a radical cation that initiates the intramolecular C(sp3)–N bond forming reaction. “HFIP is a fascinating yet intriguing ...

In a collaborative effort, researchers at the University of Amsterdam and the HFML-FELIX institute in Nijmegen have been able ...

To address the reaction mechanisms that could plausibly explain ... In short, the dehydrogenation of the β-ethyl groups followed by the intramolecular electrocyclization of the resulting ethenyl ...

This is followed by an intramolecular proton transfer ... including groundbreaking concepts, mechanisms, methods, materials, reactions, and applications. All articles are diamond open access ...

Although vinyl cations have been studied for more than 50 years, until now their use as reagents was limited to intramolecular reactions and reactions with heteroatom solvents. Because they are so ...

Superhydrides are materials that can store significantly more hydrogen than conventional hydrides and present a highly ...