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突破传统:耦合色散与氢键作用的缔合流体热力学微扰理论新探
在开发氢键流体状态方程时,色散与氢键引力的耦合常被忽视。研究人员基于 Wertheim 热力学微扰理论(TPT)开展相关研究,将两者耦合纳入理论推导。结果显示该理论有反直觉预测。这为更准确的状态方程研究提供方向。 在化学和石油化工等行业,基于微扰 ...
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