The key cyclization of an allylic alkoxyl radical to a carbon-centered allylic radical had been detected earlier (3) and has subsequently been recognized as a "key step in hydroperoxide-amplified ...

The azide-acetal has a hydrolysis half-life of days at pH 7.4 and can be conveniently synthesized and incorporated into delivery vectors, however after in situ reduction with DTT it hydrolyzes with a ...